氯三溴甲烷
外观
氯三溴甲烷 | |
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识别 | |
CAS号 | 594-15-0 |
性质 | |
化学式 | CBr3Cl |
摩尔质量 | 287.18 g·mol−1 |
熔点 | 54 °C(327 K)[1] |
沸点 | 55 °C(328 K)(18 mmHg)[1] 158.5 °C(431.6 K)[2] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
氯三溴甲烷是一种有机化合物,化学式为CBr3Cl。它与烯烃反应,以溴和氯二溴甲基加成。[3][4]
制备
[编辑]氯三溴甲烷可由四氯化碳和三溴化铝回流反应得到,[1]或通过氯代环己烷和四溴化碳在三溴化铁的催化下反应制得。[5]
二溴甲醛肟和氯化汞水溶液反应,再和溴、乙酸钠反应,得到亚硝基氯二溴甲烷,再与溴回流反应,也能得到氯三溴甲烷。[6]
参考文献
[编辑]- ^ 1.0 1.1 1.2 Ryuichi Tanaka, Shì-Qín Zhèng, Kenji Kawaguchi, Takehide Tanaka. Nucleophilic attack on halogeno(phenyl)acetylenes by halide ions. J. Chem. Soc., Perkin Trans. 2. 1980, (11): 1714–1720 [2021-11-02]. ISSN 0300-9580. doi:10.1039/P29800001714 (英语).
- ^ "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2021-11-02].
- ^ Bo Chen, Cheng Fang, Peng Liu, Joseph M. Ready. Rhodium-Catalyzed Enantioselective Radical Addition of CX 4 Reagents to Olefins. Angewandte Chemie International Edition. 2017-07-17, 56 (30): 8780–8784 [2021-11-02]. PMC 5672916 . PMID 28544237. doi:10.1002/anie.201704074. (原始内容存档于2021-11-05) (英语).
- ^ Vasil'eva, T. T.; Dostovalova, V. I.; Germanova, L. F.; Nelyubin, B. V. Radical addition of polyhalomethanes to olefins and dienes. Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1984. 1810-1814. ISSN 0002-3353.
- ^ K. B. Yoon, J. K. Kochi. Catalytic bromide and iodide exchange of alkyl chlorides with hydrogen bromide and hydrogen iodide. The Journal of Organic Chemistry. 1989-06, 54 (13): 3028–3036 [2021-11-02]. ISSN 0022-3263. doi:10.1021/jo00274a013. (原始内容存档于2021-11-05) (英语).
- ^ Katritzky, A.R.; Gilchrist, T.L.; Meth-Cohn, O.; Rees, C.W. Comprehensive Organic Functional Group Transformations. Comprehensive Organic Functional Group Transformations. Elsevier Science. 1995: 222 [2021-11-02]. ISBN 978-0-08-042704-1. (原始内容存档于2021-11-04).
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