环癸烯
| 环癸烯 | |||
|---|---|---|---|
| |||
| IUPAC名 (E)-Cyclodecene, (Z)-Cyclodecene | |||
| 别名 | cis-Cyclodecene, trans-Cyclodecene | ||
| 识别 | |||
| CAS号 | 3618-12-0  2198-20-1（E） 935-31-9（Z）
| ||
| ChemSpider | 4517575 | ||
| SMILES |
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| 性质 | |||
| 化学式 | C10H18 | ||
| 摩尔质量 | 138.25 g·mol−1 | ||
| 密度 | 0.887 g/cm−3（0 °C）[1] 0.8681 g/cm−3（E, 20 °C）[2] 0.8743 g/cm−3（Z, 20 °C）[2] | ||
| 沸点 | 143—144 °C（416—417 K）[1] 198—199 °C（471—472 K）[3] 194—195 °C（467—468 K）[4] | ||
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |||
性质
[编辑]环癸烯具有烯烃的通性，如可以发生臭氧化反应[5]、和卤素的加成反应[6][7]、环氧化反应[8]等。
参见
[编辑]参考文献
[编辑]- ^ 1.0 1.1 Willstatter, Richard; Veraguth, Hans. Cyclooctane Series. II. Communication. Berichte der Deutschen Chemischen Gesellschaft, 1907. 40. 959-970. ISSN: 0365-9496.
- ^ 2.0 2.1 Schenker, Prelog, K.; Gunthard, H. H. Carbon rings. LX. The ten-membered ring. V. Helvetica Chimica Acta, 1952. 35: 1598-1615. ISSN: 0018-019X.
- ^ Richard B. Turner, W. R. Meador. Heats of Hydrogenation. IV. Hydrogenation of Some cis- and trans-Cycloölefins 1. Journal of the American Chemical Society. 1957-08, 79 (15): 4133–4136 [2020-05-02]. ISSN 0002-7863. doi:10.1021/ja01572a042 （英语）.
- ^ A. T. Blomquist, Robert E. Burge, Arthur C. Sucsy. Many-Membered Carbon Rings. V. Cyclodecyne, cis- and trans-Cyclodecene and Related Compounds 1. Journal of the American Chemical Society. 1952-07, 74 (14): 3636–3642 [2020-05-02]. ISSN 0002-7863. doi:10.1021/ja01134a051. （原始内容存档于2019-12-30） （英语）.
- ^ Karl Griesbaum, Willi Volpp, Reinhard Greinert, Hans Joachim Greunig, Juergen Schmid, Henning Henke. Ozonolysis of tetrasubstituted ethylenes, cycloolefins, and conjugated dienes on polyethylene. The Journal of Organic Chemistry. 1989-01, 54 (2): 383–389 [2020-05-02]. ISSN 0022-3263. doi:10.1021/jo00263a023 （英语）.
- ^ Tarchini, Claudio; Tran Dinh An; Jan, Gerald; Schlosser, Manfred. Base-promoted elimination reactions. Part 8. Hydroxide-promoted hydrogen halide cleavage of vic-dihalides under heterogeneous conditions: reaction outcome due to surprising solvent and metal effects. Helvetica Chimica Acta, 1979. 62 (2): 635-640. ISSN: 0018-019X.
- ^ Kaushik, M. P.; Polshettiwar, Vivek. N-Octylquinolinium tribromide: a task specific quinoline based ionic liquid as a new brominating agent. Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 2006. 45B (11): 2542-2545. ISSN: 0376-4699.
- ^ Tatiana R. Amarante, Patrícia Neves, Filipe A. Almeida Paz, Martyn Pillinger, Anabela A. Valente, Isabel S. Gonçalves. A dinuclear oxomolybdenum(VI) complex, [Mo2O6(4,4′-di-tert-butyl-2,2′-bipyridine)2], displaying the {MoO2(μ-O)2MoO2}0 core, and its use as a catalyst in olefin epoxidation. Inorganic Chemistry Communications. 2012-06, 20: 147–152 [2020-05-02]. doi:10.1016/j.inoche.2012.02.038 （英语）.