硫酸根配合物

Some bonding modes in sulfate complexes.

硫酸根配合物是含一个或多个硫酸根配体的配位化合物，其中硫酸根以其氧原子与金属离子配位。^[1]硫酸根作为单齿配体或者螯合配体较为常见，例如[Co(tren)(NH₃)(SO₄)]⁺^[2]和Co(phen)₂SO₄；^[3]硫酸根的四个氧也可以全部和金属配位，如一些Dawson型的多酸盐，[S₂Mo₁₈O₆₂]^4-。^[4]

一些硫酸根配合物的未配位氧对质子化敏感。^[5]

参考文献

^ Papatriantafyllopoulou, Constantina; Aromi, Guillem; Tasiopoulos, Anastasios J.; Nastopoulos, Vassilios; Raptopoulou, Catherine P.; Teat, Simon J.; Escuer, Albert; Perlepes, Spyros P. Use of the Sulfato Ligand in 3d‐Metal Cluster Chemistry: A Family of Hexanuclear Nickel(II) Complexes with 2‐Pyridyl‐Substituted Oxime Ligands. European Journal of Inorganic Chemistry. 2007, 2007 (18): 2761–2774. doi:10.1002/ejic.200700063.
^ Chun, Hyungphil; Jackson, W. Gregory; McKeon, Josephine A.; Somoza, Fernando B.; Bernal, Ivan. The Interaction between Amminehalocobalt(III) Cations and Polythionate Anions: Hydrogen-Bonding Patterns and S–S Bond Cleavage Reactions. European Journal of Inorganic Chemistry. 2000, 2000: 189–193. doi:10.1002/(SICI)1099-0682(200001)2000:1<189::AID-EJIC189>3.0.CO;2-V.
^ Zhong, Kai-Long. Bis(1,10-phenanthroline-κ² N , N ′)(sulfato-κ² O , O ′)cobalt(II) propane-1,2-diol monosolvate. Acta Crystallographica Section e Structure Reports Online. 2013, 69 (Pt 1): m26. PMC 3588351 . PMID 23476325. doi:10.1107/S1600536812049616.
^ Juraja, Suzy; Vu, Truc; Richardt, Peter J. S.; Bond, Alan M.; Cardwell, Terence J.; Cashion, John D.; Fallon, Gary D.; Lazarev, Georgii; Moubaraki, Boujemaa; Murray, Keith S.; Wedd, Anthony G. Electrochemical, Spectroscopic, Structural, and Magnetic Characterization of the Reduced and Protonated α-Dawson Anions in [Fe(η⁵-C₅Me₅)₂]₅[HS₂Mo₁₈O₆₂]·3HCONMe₂·2Et₂O and [NBu₄]₅[HS₂Mo₁₈O₆₂]·2H₂O¹. Inorganic Chemistry. 2002, 41 (5): 1072–1078. PMID 11874340. doi:10.1021/ic010780s.
^ Scheidt, W. Robert; Lee, Young Ja; Finnegan, Michael G. Reactions of Sulfur Dioxide with Iron Porphyrinates and the Crystal Structure of (Hydrogen sulfato)(tetraphenylporphinato)iron(III) Hemibenzene Solvate. Inorganic Chemistry. 1988, 27 (26): 4725–4730. doi:10.1021/ic00299a010.

[1] Papatriantafyllopoulou, Constantina; Aromi, Guillem; Tasiopoulos, Anastasios J.; Nastopoulos, Vassilios; Raptopoulou, Catherine P.; Teat, Simon J.; Escuer, Albert; Perlepes, Spyros P. Use of the Sulfato Ligand in 3d‐Metal Cluster Chemistry: A Family of Hexanuclear Nickel(II) Complexes with 2‐Pyridyl‐Substituted Oxime Ligands. European Journal of Inorganic Chemistry. 2007, 2007 (18): 2761–2774. doi:10.1002/ejic.200700063.

[2] Chun, Hyungphil; Jackson, W. Gregory; McKeon, Josephine A.; Somoza, Fernando B.; Bernal, Ivan. The Interaction between Amminehalocobalt(III) Cations and Polythionate Anions: Hydrogen-Bonding Patterns and S–S Bond Cleavage Reactions. European Journal of Inorganic Chemistry. 2000, 2000: 189–193. doi:10.1002/(SICI)1099-0682(200001)2000:1<189::AID-EJIC189>3.0.CO;2-V.

[3] Zhong, Kai-Long. Bis(1,10-phenanthroline-κ² N , N ′)(sulfato-κ² O , O ′)cobalt(II) propane-1,2-diol monosolvate. Acta Crystallographica Section e Structure Reports Online. 2013, 69 (Pt 1): m26. PMC 3588351 . PMID 23476325. doi:10.1107/S1600536812049616.

[4] Juraja, Suzy; Vu, Truc; Richardt, Peter J. S.; Bond, Alan M.; Cardwell, Terence J.; Cashion, John D.; Fallon, Gary D.; Lazarev, Georgii; Moubaraki, Boujemaa; Murray, Keith S.; Wedd, Anthony G. Electrochemical, Spectroscopic, Structural, and Magnetic Characterization of the Reduced and Protonated α-Dawson Anions in [Fe(η⁵-C₅Me₅)₂]₅[HS₂Mo₁₈O₆₂]·3HCONMe₂·2Et₂O and [NBu₄]₅[HS₂Mo₁₈O₆₂]·2H₂O¹. Inorganic Chemistry. 2002, 41 (5): 1072–1078. PMID 11874340. doi:10.1021/ic010780s.

[5] Scheidt, W. Robert; Lee, Young Ja; Finnegan, Michael G. Reactions of Sulfur Dioxide with Iron Porphyrinates and the Crystal Structure of (Hydrogen sulfato)(tetraphenylporphinato)iron(III) Hemibenzene Solvate. Inorganic Chemistry. 1988, 27 (26): 4725–4730. doi:10.1021/ic00299a010.

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