磷化铈
外观
磷化铈 | ||
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识别 | ||
CAS号 | 25275-75-6 | |
性质 | ||
化学式 | CeP | |
摩尔质量 | 171.09 g·mol−1 | |
外观 | 深灰色晶体[1] | |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
磷化铈是一种无机化合物,化学式为CeP,它是铈的磷化物之一。它可由二氧化铈和磷化氢在氢气的存在下于1300 °C反应得到,[2]或由磷化钠和氯化铈在700~800 °C反应得到。[1]它在空气中在900 °C以上会氧化为单斜的CePO4。[2]它在石英安瓿内和碘反应,可以得到CeSiP3。[3]
参考文献
[编辑]- ^ 1.0 1.1 Rowley, Adrian T.; Parkin, Ivan P. Convenient synthesis of lanthanide and mixed lanthanide phosphides by solid-state routes involving sodium phosphide. Journal of Materials Chemistry (Royal Society of Chemistry (RSC)). 1993, 3 (7): 689. ISSN 0959-9428. doi:10.1039/jm9930300689.
- ^ 2.0 2.1 Vasil'eva, I. G.; Mironov, K. E.; Mironov, Yu. I. Properties of cerium monophosphide(俄文). Redkozemel. Metal. Ikh Soedin., Mater. Vses. Simp., 1970: 160-165. CODEN 26HIAV.
- ^ Mironov, K. E.; Abdullin, R. V. Formation and chemical transfer of cerium silicon phosphide (CeSiP3)(俄文). Zhurnal Neorganicheskoi Khimii, 1980. 25 (8): 2062-2066.
延伸阅读
[编辑]
- Pavel S. Chizhov, Nellie R. Khasanova, Michael Baitinger, Walter Schnelle, Yuri Prots, Ulrich Burkhardt, Evgeny V. Antipov, Yuri Grin. Ce 4 (P 1- x Si x ) 3- z : A First Example for the Stabilization of the Anti-Th 3 P 4 Type Structure by Substitution in the Non-Metal Substructure. Inorganic Chemistry. 2006-09-01, 45 (18): 7210–7216 [2021-12-27]. ISSN 0020-1669. doi:10.1021/ic060726h (英语).