1-氯-3-溴丙烷
| 1-氯-3-溴丙烷 | |
|---|---|
| |
| 别名 | 1-溴-3-氯丙烷 |
| 识别 | |
| CAS号 | 109-70-6 
|
| PubChem | 8006 |
| ChemSpider | 7715 |
| SMILES |
|
| UN编号 | 2688 |
| RTECS | TX4113000 |
| 性质 | |
| 化学式 | C3H6BrCl |
| 摩尔质量 | 157.44 g·mol−1 |
| 外观 | 无色液体 |
| 密度 | 1.5222 g·cm−3（20 °C）[1] |
| 熔点 | −58.90 °C（214.25 K）[2] |
| 沸点 | 143.3 °C（416.4 K）[3] |
| 危险性 | |
GHS危险性符号   
| |
| GHS提示词 | 警告 |
| H-术语 | H226, H302, H315, H319, H331, H332, H335, H341, H412 |
| P-术语 | P201, P202, P210, P233, P240, P241, P242, P243, P261, P264, P270, P271, P273, P280 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
1-氯-3-溴丙烷是一种有机卤化物，化学式为BrCH2CH2CH2Cl。它是无色的液体，由烯丙基氯和溴化氢的自由基加成反应制得。[4]
- H2C=CHCH2Cl + HBr —(PhCO2)2→ BrCH2CH2CH2Cl
它是一种烷基化试剂，可以用于引入ClCH2CH2CH2-[5]或-CH2CH2CH2-基团。[6]
参考文献
[编辑]- ^ Afanas'ev, I. B.; Beer, A. A. Telomerization of bromochloromethane with ethylene. Zhurnal Vsesoyuznogo Khimicheskogo Obshchestva im. D. I. Mendeleeva, 1962. 7: 595-597. ISSN: 0373-0247.
- ^ "Hazardous Substances Data Bank" data were obtained from the National Library of Medicine (US). Retrieved from SciFinder. [2019-9-6]
- ^ Cash, Gordon G.; Hartigan, Suzanne; Tunkel, Jay. Normal boiling points of haloalkanes from electrotopological state indices. Toxicological & Environmental Chemistry. 2008, 90 (6): 1073–1089. ISSN 0277-2248. doi:10.1080/02772240701862116.
- ^ Dagani, M. J.; Barda, H. J.; Benya, T. J.; Sanders, D. C., Bromine Compounds, Ullmann's Encyclopedia of Industrial Chemistry, Weinheim: Wiley-VCH, 2005, doi:10.1002/14356007.a04_405
- ^ Evans, D. A.; Domeier, L. A. Endocyclic Enamine Synthesis: N-Methyl-2-Phenyl-δ2-tetrahydropyridine. Org. Synth. 1974, 54: 93. doi:10.15227/orgsyn.054.0093.
- ^ Glass, D. B.; Weissberger, A. Julolidine. Org. Synth. 1946, 26: 40. doi:10.15227/orgsyn.026.0040.