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2-三氟甲基联苯

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2-三氟甲基联苯
识别
CAS号 362-59-4  checkY
SMILES
 
  • FC(F)(F)C=1C=CC=CC1C=2C=CC=CC2
性质
化学式 C13H9F3
摩尔质量 222.21 g·mol−1
熔点 15 °C(288 K)[1]
沸点 114 °C(387 K)(19 torr)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

2-三氟甲基联苯是一种有机化合物,化学式为C13H9F3。它可由2-三氟甲基卤苯和苯硼酸经偶合反应制得,[2][3]2'-三氟甲基联苯-2-甲酸的脱羧反应也能得到2-三氟甲基联苯。[4]它和氢气在催化剂存在下反应,可以得到1-三氟甲基-2-环己基环己烷,主产物具有R,R构型。[5]它和氢化铝锂五氯化铌催化下反应,得到9H-[6][7]

参考文献

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  6. ^ Kohei Fuchibe, Ken Mitomi, Ryo Suzuki, Takahiko Akiyama. CC Coupling Reactions of Superstrong CF 3 Groups with C(sp 2 )-H Bonds: Reactivity and Synthetic Utility of Zero-Valent Niobium Catalyst. Chemistry - An Asian Journal. 2008-02-01, 3 (2): 261–271 [2021-03-20]. doi:10.1002/asia.200700333 (英语). 
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