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乙酰丙酮鑥

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乙酰丙酮鑥
識別
CAS號 17966-84-6  checkY
性質
化學式 C15H21LuO6
摩爾質量 472.29 g·mol−1
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

乙酰丙酮鑥是一種配位化合物,化學式為Lu(C5H7O2)3,或簡寫為Lu(acac)3,它和乙酰丙酮鐿同構。[1]它可由三烷氧基鑭和乙酰丙酮反應製得。[2]

它的二水合物和鄰菲囉啉(phen)或2,2'-聯吡啶(dipy)在乙醇溶液中回流,可以得到混合配體配合物Lu(acac)3(phen)和Lu(caca)3(dipy)。[3]

參考文獻

[編輯]
  1. ^ Trembovetskii, G. V.; Martynenko, L. I.; Murav'eva, I. A.; Spitsyn, V. I. Synthesis and study of volatile rare earth acetylacetonates(俄文). Doklady Akademii Nauk SSSR, 1984. 277 (6): 1411-1414. ISSN 0002-3264.
  2. ^ Gavrilenko, V. V.; Chekulaeva, L. A.; Savitskaya, I. A.; Garbuzova, I. A. Synthesis of yttrium, lanthanum, neodymium, praseodymium and lutetium alkoxides and acetylacetonates(俄文). Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1992. 11: 2490-2493. ISSN 1026-3500.
  3. ^ Andrey Yu. Rogachev, Andrey V. Mironov, Sergey I. Troyanov, Natalia P. Kuzmina, Alexander V. Nemukhin. Synthesis, crystal structures and theoretical study of mixed ligand complexes of lanthanides acetylacetonates with o-phenanthroline and 2,2′-dipyridyl: The unexpected inverted electrostatic trend in stability. Journal of Molecular Structure. 2006-05, 789 (1-3): 187–194 [2021-09-20]. doi:10.1016/j.molstruc.2005.12.026. (原始內容存檔於2020-02-25) (英語).