1,3-苯並二氧戊環-5-硼酸

1,3-苯並二氧戊環-5-硼酸
	IUPAC名; 1,3-苯並二噁環戊熳-5-硼酸
別名	3,4-甲二氧基苯硼酸; 3,4-亞甲基二氧基苯硼酸; 苯並二噁茂-5-硼酸
識別
CAS號	94839-07-3
性質
化學式	C7H7BO4
摩爾質量	165.94 g·mol−1
外觀	無色晶體
熔點	238-240 °C
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

1,3-苯並二氧戊環-5-硼酸是一種有機化合物，化學式為C₇H₇BO₄。它可由5-溴-1,3-苯並二氧戊環為原料，和鎂反應後再與硼酸三丁酯反應，水解後得到^[1]；或以1,3-苯並二氧戊環-5-胺為原料，重氮化後和二硼酸反應製得。^[2]它和氟化氫鉀反應，可以得到1,3-苯並二氧戊環-5-基三氟硼酸鉀。^[3]

參考文獻[編輯]

^ ^1.0 ^1.1 ^1.2 Mg Banwell, Cj Cowden. Convergent Routes to the [1,3]Dioxolo[4,5-j]phenanthridin-6(5H)-one and 2,3,4,4a-Tetrahydro[1,3]dioxolo[4,5-j]phenanthridin-6(5H)-one Nuclei. Application to Syntheses of the Amaryllidaceae Alkaloids Crinasiadine, N-Methylcrinasiadine and Trisphaeridine. Australian Journal of Chemistry. 1994, 47 (12): 2235 [2022-10-10]. ISSN 0004-9425. doi:10.1071/CH9942235 （英語）.
^ William Erb, Mathieu Albini, Jacques Rouden, Jérôme Blanchet. Sequential One-Pot Access to Molecular Diversity through Aniline Aqueous Borylation. The Journal of Organic Chemistry. 2014-11-07, 79 (21): 10568–10580 [2022-10-10]. ISSN 0022-3263. doi:10.1021/jo501665e. （原始內容存檔於2022-10-16）（英語）.
^ Shigeki Matsunaga, Ayako Nakano, Yukino Okabe, Keitaro Matsuoka, Narumi Komami, Keito Watanabe, Masahiro Kojima, Tatsuhiko Yoshino. Generation of Monoaryl-λ3-iodanes from Arylboron Compounds through ipso-Substitution. HETEROCYCLES. 2021, 103 (2): 670 [2022-10-10]. ISSN 0385-5414. doi:10.3987/COM-20-S(K)45. （原始內容存檔於2022-10-14）（英語）.

[banwell-1] 1.0 ^1.1 ^1.2 Mg Banwell, Cj Cowden. Convergent Routes to the [1,3]Dioxolo[4,5-j]phenanthridin-6(5H)-one and 2,3,4,4a-Tetrahydro[1,3]dioxolo[4,5-j]phenanthridin-6(5H)-one Nuclei. Application to Syntheses of the Amaryllidaceae Alkaloids Crinasiadine, N-Methylcrinasiadine and Trisphaeridine. Australian Journal of Chemistry. 1994, 47 (12): 2235 [2022-10-10]. ISSN 0004-9425. doi:10.1071/CH9942235 （英語）.

[2] William Erb, Mathieu Albini, Jacques Rouden, Jérôme Blanchet. Sequential One-Pot Access to Molecular Diversity through Aniline Aqueous Borylation. The Journal of Organic Chemistry. 2014-11-07, 79 (21): 10568–10580 [2022-10-10]. ISSN 0022-3263. doi:10.1021/jo501665e. （原始內容存檔於2022-10-16）（英語）.

[3] Shigeki Matsunaga, Ayako Nakano, Yukino Okabe, Keitaro Matsuoka, Narumi Komami, Keito Watanabe, Masahiro Kojima, Tatsuhiko Yoshino. Generation of Monoaryl-λ3-iodanes from Arylboron Compounds through ipso-Substitution. HETEROCYCLES. 2021, 103 (2): 670 [2022-10-10]. ISSN 0385-5414. doi:10.3987/COM-20-S(K)45. （原始內容存檔於2022-10-14）（英語）.

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