丙酸銫
| 丙酸銫 | |
|---|---|
| |
| 識別 | |
| CAS號 | 38869-24-8 
|
| 性質 | |
| 化學式 | C3H5CsO2 |
| 摩爾質量 | 205.98 g·mol−1 |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
丙酸銫是銫的丙酸鹽，化學式為C2H5COOCs。它可由碳酸銫和丙酸反應後蒸發、乾燥、結晶得到。[1]它可用於有機合成，如環氧化物的開環及構型翻轉。[2][3]它也能用於丙酸復鹽（配鹽）的製備。[4]
參考文獻
[編輯]- ^ Plyushchev, V. E.; Savel'eva, M. V.; Shakhno, I. V. Cesium propionate, butyrate, and isovalerate. Zhurnal Neorganicheskoi Khimii, 1962. 7: 2078-2081.
- ^ Wim H. Kruizinga, Bert Strijtveen, Richard M. Kellogg. Cesium carboxylates in dimethyl formamide. Reagents for introduction of hydroxyl groups by nucleophilic substitution and for inversion of configuration of secondary alcohols. The Journal of Organic Chemistry. 1981-10, 46 (21): 4321–4323 [2021-07-03]. ISSN 0022-3263. doi:10.1021/jo00334a055 （英語）.
- ^ David O Arbelo, José A Prieto. Cesium propionate as an epoxide cleavage and inversion reagent. Tetrahedron Letters. 2002-05, 43 (22): 4111–4114 [2021-07-03]. doi:10.1016/S0040-4039(02)00739-6 （英語）.
- ^ Viktor N. Serezhkin, Mikhail S. Grigoriev, Aleksey R. Abdulmyanov, Aleksandr M. Fedoseev, Anton V. Savchenkov, Sergey Yu. Stefanovich, Larisa B. Serezhkina. Syntheses, Crystal Structures, and Nonlinear Optical Activity of Cs 2 Ba[AnO 2 (C 2 H 5 COO) 3 ] 4 (An = U, Np, Pu) and Unprecedented Octanuclear Complex Units in KR 2 (H 2 O) 8 [UO 2 (C 2 H 5 COO) 3 ] 5 (R = Sr, Ba). Inorganic Chemistry. 2017-06-19, 56 (12): 7151–7160 [2021-07-03]. ISSN 0020-1669. doi:10.1021/acs.inorgchem.7b00809. （原始內容存檔於2022-03-05） （英語）.