硝酸氙
硝酸氙是一種使二氟化氙與無水硝酸反應製得的過渡化合物。 儘管二硝酸氙 (Xe(NO3)2) 尚未被分離，它的一硝酸鹽：硝酸氟化氙(XeFNO3)已經進行了研究。
製備
[編輯]嘗試生產二硝酸氙的方法： [1]
XeF2 + 2HNO3 → Xe(NO3)2 + 2HF[2][3]
這個反應取得了紅棕色的固體，在23 °C 下變藍，持續很短時間，然後猛烈分解。[2]
這個分解反應是：
- Xe(NO3)2 → Xe + O2NOONO2 (不穩定的氮過氧化物)
但是，確實存在混合硝酸鹽FXeONO2。 [1] 這個化合物被稱為一硝酸氟化氙[4] 或氟硝酸化氙。[5]
參考資料
[編輯]- ^ 1.0 1.1 Moran, Matthew D. Synthesis and Structural Characterization of new Xenon(II) Compounds and the Use of a Xenon(II) Cation as an Oxidant for the Preparation of Halogenated Hydrocarbons (PDF). McMaster University. 2007: 42, 99–145 [4 Oct 2014]. （原始內容存檔 (PDF)於2016-03-03）.
- ^ 2.0 2.1 Eisenberg, Max; Darryl D. DesMarteau. The reaction of xenon difluoride with some strong oxy-acids. Inorganic and Nuclear Chemistry Letters. 1970, 6 (1): 29–34. ISSN 0020-1650. doi:10.1016/0020-1650(70)80279-3.
- ^ Zefirov, N. S; Gakh, A. A.; Zhdankin, V. V.; Stang, P. J. Interaction of Fluoroxenonium Triflate, Fluorosulfate, and Νitrate with Alkenes. Stereochemical Evidence for the Electrophilic Noble Gas Cation Addition to the Carbon-Carbon Double Bond. J. Org. Chem. 1991, 56: 1416–1418. doi:10.1021/jo00004a015.
- ^ Atta-ur-Rahman. Advances in Organic Synthesis: Modern Organofluorine Chemistry-Synthetic Aspects. Bentham Science Publishers. 2006-01-01: 78 [5 October 2014]. ISBN 9781608051984.
- ^ Moran, Matthew D.; David S. Brock; Hélène P. A. Mercier; Gary J. Schrobilgen. Xe3OF3+, a Precursor to a Noble-Gas Nitrate; Syntheses and Structural Characterizations of FXeONO2, XeF2·HNO3, and XeF2·N2O4. Journal of the American Chemical Society. 2010, 132 (39): 13823–13839. ISSN 0002-7863. PMID 20843046. doi:10.1021/ja105618w.