硒氰酸银

硒氰酸银
英文名	Silver(I) selenocyanate
识别
CAS号	5169-33-5
性质
化学式	CAgNSe
摩尔质量	212.85 g·mol−1
相关物质
其他阴离子	氰化银; 氰酸银; 雷酸银; 硫氰酸银
其他阳离子	硒氰酸亚铜
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

硒氰酸银是一种无机化合物，化学式为AgNCSe，可由复分解反应制备。新制的硒氰酸银可以和热的硝酸银及高氯酸银溶液反应，分别生成(Ag₃NCSe)(NO₃)₂和(Ag₂NCSe)ClO₄。^[1]硒氰酸银在390 K按下式分解：2 AgSeCN → Ag₂Se + Se + (CN)₂↑。^[2]它和CH₃OC(O)SCl反应，得到CH₃OC(O)SSeCN。^[3]

参考文献

^ Golub, A. M.; Skopenko, V. V. Cationic selenocyanate complexes of silver. Doklady Akademii Nauk SSSR, 1961. 138: 601-604. ISSN: 0002-3264.
^ E. A. Rietman. Conduction properties of silver and copper pseudohalides. Journal of Materials Science Letters. 1985-05, 4 (5): 542–544 [2019-10-30]. ISSN 0261-8028. doi:10.1007/BF00720027 （英语）.
^ Lin Du, Li Yao, Maofa Ge. Two Novel Species, (Methoxycarbonyl)sulfenyl Thiocyanate and (Methoxycarbonyl)sulfenyl Selenocyanate: Spectroscopic Characterization by Photoelectron Spectroscopy and Quantum Chemical Investigation. European Journal of Inorganic Chemistry. 2007-10, 2007 (28): 4514–4519 [2019-10-30]. doi:10.1002/ejic.200700455 （英语）.

[1] Golub, A. M.; Skopenko, V. V. Cationic selenocyanate complexes of silver. Doklady Akademii Nauk SSSR, 1961. 138: 601-604. ISSN: 0002-3264.

[2] E. A. Rietman. Conduction properties of silver and copper pseudohalides. Journal of Materials Science Letters. 1985-05, 4 (5): 542–544 [2019-10-30]. ISSN 0261-8028. doi:10.1007/BF00720027 （英语）.

[3] Lin Du, Li Yao, Maofa Ge. Two Novel Species, (Methoxycarbonyl)sulfenyl Thiocyanate and (Methoxycarbonyl)sulfenyl Selenocyanate: Spectroscopic Characterization by Photoelectron Spectroscopy and Quantum Chemical Investigation. European Journal of Inorganic Chemistry. 2007-10, 2007 (28): 4514–4519 [2019-10-30]. doi:10.1002/ejic.200700455 （英语）.

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