乙酸铥
| 乙酸铥 | |
|---|---|
| |
| 英文名 | Thulium(III) acetate |
| 别名 | 醋酸铥 |
| 识别 | |
| CAS号 | 39156-80-4 
|
| 性质 | |
| 化学式 | Tm(CH3COO)3 |
| 外观 | 晶体 |
| 溶解性（水） | 可溶 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
乙酸铥是铥的乙酸盐，化学式为Tm(CH3COO)3，它以无水物和四水合物[1]的形式存在。
性质
[编辑]乙酸铥和乙酰丙酮铁在丁二醇中于300 °C反应，可以得到六方晶系的TmFeO3。[2]
- Tm(CH3COO)3 + 3 CF3COOH → Tm(CF3COO)3 + 3 CH3COOH
参考文献
[编辑]- ^ K. I. Petrov, M. G. Zaitseva, L. M. Sukova. Spectroscopic study of thulium acetate tetrahydrate single crystals. Journal of Applied Spectroscopy. 1971-08-01, 15 (2): 1058–1060 [2019-02-01]. ISSN 1573-8647. doi:10.1007/BF00607309 （英语）.
- ^ Masashi Inoue, Toshihiro Nishikawa, Tomohiro Nakamura, Tomoyuki Inui. Glycothermal Reaction of Rare-Earth Acetate and Iron Acetylacetonate: Formation of Hexagonal ReFeO3. Journal of the American Ceramic Society. 1997, 80 (8): 2157–2160 [2019-02-01]. ISSN 1551-2916. doi:10.1111/j.1151-2916.1997.tb03103.x （英语）.
- ^ S. I. Gutnikov, E. V. Karpova, M. A. Zakharov, A. I. Boltalin. Thulium(III) trifluoroacetates Tm(CF3COO)3 · 3H2O and Tm2(CF3COO)6 · 2CF3COOH · 3H2O: Synthesis and crystal structure. Russian Journal of Inorganic Chemistry. 2006-04-01, 51 (4): 541–548 [2019-02-01]. ISSN 1531-8613. doi:10.1134/S0036023606040061 （英语）.
拓展阅读
[编辑]
- Mondry, A., & Bukietyńska, K. (2003). The power and limits of the Judd—Ofelt theory: a case of Pr3+ and Tm3+ acetates and dipicolinates. Molecular Physics, 101(7), 923-934.