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碘酸镎(IV)

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碘酸镎(IV)
识别
CAS号 39980-75-1  checkY
性质
化学式 Np(IO3)4
摩尔质量 936.60 g·mol⁻¹
外观 根据晶体角度不同呈现灰色至绿色至黑色转变[1]
密度 6.006 g·cm-3（-80 °C）[2]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

碘酸镎(IV)是一种无机化合物，有放射性，化学式为Np(IO3)4，Np(IV)的配位数为8。[3]它的无水物或水合物均可由Np4+和碘酸盐反应制得，其无水物属四方晶系P42/n空间群。[2]

参考文献

[编辑]
  1. ^ Travis Henry Bray. Crossroads and Terminations in Transuranium Chemistry. Auburn University, 2008.
  2. ^ 2.0 2.1 Travis H. Bray, Jie Ling, Eun Sang Choi, James S. Brooks, James V. Beitz, Richard E. Sykora, Richard G. Haire, David M. Stanbury, and Thomas E. Albrecht-Schmitt. Critical Role of Water Content in the Formation and Reactivity of Uranium, Neptunium, and Plutonium Iodates under Hydrothermal Conditions: Implications for the Oxidative Dissolution of Spent Nuclear Fuel. Inorg. Chem. 2007, 46, 9, 3663–3668. doi:10.1021/ic070170d
  3. ^ Diwu, Juan; Wang, Shuao; Liao, Zuolei; Burns, Peter C.; Albrecht-Schmitt, Thomas E. (2010). Cerium(IV), Neptunium(IV), and Plutonium(IV) 1,2-Phenylenediphosphonates: Correlations and Differences between Early Transuranium Elements and Their Proposed Surrogates. Inorganic Chemistry, 49(21), 10074–10080. doi:10.1021/ic1015912
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